| Index | Valentine | Arizona | National |
| Average Test Scores | n/a | 43% | 48% |
| Student/Teacher ratio | n/a | 18:1 | 16:1 |
| Total public schools | n/a | 1,863 | 79,221 |
| Total private schools | n/a | 316 | 24,874 |
| Total post-secondary schools | n/a | 148 | 7,963 |

| Index | Valentine | Arizona | National |
| Completed 8th grade | 98.0% | 83.7% | 84.3% |
| Completed high school | 30.0% | 82.2% | 83.0% |
| Completed some college | 18.0% | 62.0% | 59.4% |
| Completed associate degree | 8.0% | 36.5% | 38.5% |
| Completed bachelors | 2.0% | 28.0% | 30.3% |
| Completed masters | 2.0% | 10.4% | 11.5% |
| Completed professional degree | 0.0% | 2.9% | 3.3% |
| Completed doctorate | 0.0% | 1.2% | 1.3% |
There are a total of n/a public schools, n/a private schools and n/a post-secondary schools in Valentine. Using the proficiency score averages, the average test scores for Valentine, AZ schools is n/a. The average student to teacher ratio is n/a. In Valentine, AZ, an average of 98.0% of students have completed 8th grade and an average of 30.0% have completed high school.
| City | Population | Avg. Test Scores | National Avg. |
| Peach Springs, AZ | 1,394 | 9% | 81.8% |
| Valentine, AZ | 44 | n/a |
| City | Population | Avg. Test Scores | National Avg. |
| Circle, AK | 44 | 50% | 4.2% |
| Avilla, MO | 43 | 35% | 28.1% |
| Chignik, AK | 43 | 50% | 4.2% |
| Iliamna, AK | 45 | 20% | 58.3% |
| Crestone, CO | 45 | 18% | 63.5% |
| Valentine, AZ | 44 | n/a |